Activation Energy For Surface Diffusion


This study is an attempt to understand the activation energy of an ag atom diffusing between the adjacent threefold sites on the cu(111) surface. We find a low activation energy of 0.4 ev for carbon surface diffusion on ni and co (111) planes, much lower than for bulk diffusion.

Spring2004
Spring2004 from www.owlnet.rice.edu

The activation energy for impurity atom (adatom) surface diffusion can be determined from the temperature dependence of the spacing of sputter cones. The carbon diffusion on the catalyst surface and the stability of the precursor molecules, c 2h 2 or ch 4, are investigated by ab initio plane wave density functional calculations.

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